CHEM 202 Problems Chapter 15, Fall 2011

Cl^-p .,tS . ^r A . o.'1oo I '1" 7a"-; c' at'L tt H c: Hi o. * flro ?l o.4 o..'t -x ' (^" ;c.Hro;]L'\ssJ x' [+tcrur{ *' i,t.?xt6E xo,l o. l-X -f\ .t.t x )o ) .+ n Hso !.O x X= -, ,4.;q x lo *.".1L!- OPP. lr q a4 - -3 =) [*sdj = .,t.'{tx lo f] b. o.4s ( ,loAv*'- f fo*oo'tr- It No Cr\{t 0" caqr o; + $&o * o.\ o.\ -x t^\ lNac.H.u, 1 + .. ^ - Na + Q ssue *Ca*s0r + oH o ro XX =)(.. -b a L.suror-] 'i-F "t => [ot\f , Y.}}x\-o6 q -7 =-- o.l-X L z J-- 4*, o.\ x o.l = 7.11x to6 1l ^|tJ ,.r**#t1 ? fH=1.51 W ^i - \rd -3og. 21,tit-"- ( a c, Agoo t K.,o. \-. f'-v- 5 )l )x >( >,. Z--/ o.\ Ko x o'l .l K, X O'\ .-q to i3iF"s L'*so'] , J. /(.3i a. o.og n *ub = 6.oi x n-*,q = o.ls x Nt{3 + ani$aL , .X*to' FnJ . a'6'xl-o3 N\13 + 5.pr+iol 3!q o'2S. Ellkr* *',iS-- t** u.'o o..1oo( H%HrO. H Ca t{sOa + q,o o. .l o.,{-X lrtc.us€ tH=+ + o.4oo t] t3ts t,. o.,,1 o .-1 + x No- C3 H. O. + H^O' x --Js- Ko= Lc.u.o;] Lrr.d] = ("..**) * o .. : X : .,1.3 x lo o. I x _ o.l o..{ -x -2 4.2C xlo 3.1( x lo tos 11 ,7 " Lt'l = .4 3x IH Ll 94 r'oL r-L '|| ""1* o{ r^otn ,s N o,,{511 ut\u' + o.o'{ *oL HC'o- o.2i H ci- o.o4 )^" -z . 3.trSYlo -t 33Sxlo + -z lo tlo -r x$J * ot\ .<- <- q'lixl' -o=s- lji!:':l:- .r x X o ,2S ["'**-] forr-J 6. 13 x o. Dl a.(xl-o(xo.0l , 9.\+X\O t\ "..\* o. \5 n .) I i\o'\' \-" -J * **,i t Nr\q- o.3{> f r"v+l K6 xo l X: o.t9 9.\1x ln= lo -1.06 xlo l],1 --i aY -t,J.t t. ".Sn Nt!/ 4.sofl N\LL + cr.o'{ v' oL HU' J5o r,,rL o.3X "*L =t [9{] = 1(\ -- D ='' IoH- \ -- c. ltt. 1t{.a + --Ln !t{1" ct" w^,,r : o.42S v^oL '9 s\\ + !\ c!- ----+ o.llS o.o\ o. \\S o N\\* so o. \\( ---.7 o.ltg. - x o.2s \-" I ''"'t ^.. . ^ ^\ o. 5'f> .rv -l Jc- .,.4 . ^Lt Nj\ ''r vrr o,3gs o.3ts rI o.\6 -T (.3rxt6t 11 ? fou = .lpq ts5 = ( ac'"L 1s\a ; x= o,\t 521 t f* -L 5.39 x to alf. cc(a{KA- ll I ffi = o'lla LN rUJ ------:n- I N ttu \ fh pav.- s.2Ip _\ -/ + -lrq ( fl\ is (o.01-x) (a,st r x) r =\'Z v 9v a 0. -t0 \,ii! 4.o^r" TL pc-^d ,b"lo{io'' 0.. 15.(4 ttO ,^^\- o. ! n t{L{" 0t + "o'4 11 K" H -*oo* = o 9x o'D* = 8x l-o3 *oL 0 nr.L la!* odJgd- ,: Htt o* + bo '-"1 bo* * cl0i r,) ^*{Jo* -\md.aqjL = tvl'o3 v,oL =) Ltol= f".^-t'n J^ * t';? ob'toi^' 'tt"L c-"csa&"do'r- 4** o "t* ;o\o\on- l [*Uo.] = o.?0 ,lH=-fru", t. .,lo *L +i.oH $tLo\ ,.' Exto o.d J.A , t) [r-n= o' \ xo o\ = l-o3 *oL * l<oi\ ------{ KuO\ + b.o ,-}lo o : o.-l\ il = .-) -+{ \o .-a :lx lo Q.o't +o.ot) - --1 I h,o' \ ) bH: o.rs I c . tlQ *L f(ol,\ o^J,t J *\C0D* "+ XoH -3 '3 Txlo r+ ).lO -l \xld o .\ =) f.r+croi , -149- L J 1os* +o.or) J . ?o ',.L KoH +\00.f .-t Txlo =) L<o* : o.\ * o s\ = --D +<Q. o\ + |!O . .-) ItXIO Y*oL o.os 11 = [ho*] .> L- - o-.4&I =) rukor.\ = o \ x o'o-6 + Rol\ ----e +(clo* + $o .-5 trxlo. D -ru - i" - -,r.30 -a 3 Xx \o !"oL $^n-- i v..oL ? 1J ss'trct- l\0{ -i^, tt*- ,lnto{i""'- "-fI F* I a.^r{s oli 6ss cdL'o (- Ro{ od-\al =) *Rort lMI0q + |aol{ ------+ ' ,-5 ,-L Exto lo .-3 D ,.xlo 6 i"u cxc"t ) -l -z Sxlo = l.\3xlo 11 o.o\ +o '\ - .1 -r1 =) UUo.J = 6.99 x lo- tl .,i w.L^- v',"o\eole,' J 1^o -) "1,,1 vo-Ltr : o,l xo.l = Ktl.0.{ + tlO .-2 lo z. ,1OS rlL =) xDH (-ort J: --) tH' ^2'^b ls . > | ztoo *L o.\ YL- = o.4xo. H.r.rN \ llN Nr,h -z -lo Y'\o\- (Ko = +o.2\ +Kto HaNN\ + a.1: xlo\ tl "-J" [td] =5,1'r,t6" n a lrt'10'14 ? tr*roo= o.2xo o2 = +x\o3 *.L _* tl, NN+\g + sS. -3 * x lo P\ .- 6\ 3.oxto 7 a. l.o"-"6t * t6' . ,,l.13xlo\ 11 'y L 3l *L tl-soa oiJ''L rlr.' ru s.r r\ + +f tu O.5 -z .-3 4o +xlo bx lo D .lr\n U v^L- ft-r3 $ss t1.' * .L lo .L\o -x O..rd.-A OH *,'q;ffi=*= 4r)': x: lnH I r|N NA + i|'o '2- .-3 . GxtoT^.17 /- -1 6xlo -14 -of [+vlo +x) X - \o-,T1f / ! /-\\- I Gxlo -x] =7[ovr] = \.svl-o" t1 .+ -) l{Ssq + C4r- **t8f ,tz .-t lsle tx o. 12 X -L t.(x lo uH = T.65 I :) x: oH KD xlo =) por\ ' 5.39 -.2) nYl o'lur C - /> $nL trNw3 +\ NN\ a<d '40 -5 S-Y lo ^AJ./. .) hn*$u0g= Sxli3 '^oL %'\{ -1"rv + 4fNos ------+ +!"*C * No3- -3 g SY lo --) Pt''11Ptt + Ot-\' s_ t- -t. \ \S x \o/o.l2SJ --t*. S x lo +x ;1t< 4"* -wF- .-a I =) rHsoa: txto n^ou = X,\n + S9 \J =) **"oa = -'l-o- v^"L cr*$rt4 -rtt^- *Nol h t \(l bp + bs*b*Ud Host':5 1 | -t- t \ ( Sxto;/e.tnS 1 .-.) sr!. -^ J. ?|r? = w'rv -1 s9 'T'"' .LI'* NY^- b)f.{,., \lo *',/ i\rssrq t .L G. Clxlo t c.6aylo -X Lx L =L---= =) X -- 4 \9 x\o' ^fF '$\'I G.6+xto- I l I v K"r K, 4..r1 ilqo \ L- G.6+Y\o -1 -- i.\3 x\ii 11 =) ts-- tK^- ",l*fi: = 8.\l + -!o6 \ I \ ac'a- LtO *L +4NOt oAJ"J' Simi\or- % f^l tu' JK* q *r a-. 50 *L +\Ng aA&I =) hNtJb ^Iod" i[ = 4.x3 . ,,tot *L t*s0o o,JJed :.) *o*o : 9x l-ot *oL =) frNO3 "w txt!''v) (tZi t-''t- i^ r*cn",r) At t0.; ^Y ., \*" i'* 1 \Eo+ "*;u -* *cc Jet'r\o .,,l!.r-\^ o.i\-,-- +t- )tns^q o-c,a- )"a o'*A tt^' we-o-t< o-c^A' flxs,rur{ uJ.- t']'tU'^' (^11"r'r*"u*) +{"eE $'- fbo* Co*rs orl =r [ho1' ' U" '-'' t* +e- l!tr"*3 '-c"^t li -- (x t-o' i1 -> l+\ = '4'30 o,) )s. s3 ^. 4on *t- r{ o 'l + o'4r1 \'i\-- 11 k\crtisor. ({<o= q,'i* rot)-+g*= 163"'L Noon n Ll nsvr -2- lo -E 5 xlQ tlL1trS") -L 333x\o -z 3.3)r\o -) NAOH -t 5 X l\r J <- c,lko" \la + bo Sxlo rt C\ 5 ----) (ri ' so*u) \DH / n Ll .+ 1 3.33 x\o -l l33x\o +X te.. sflH# ' lK^ = )' ^s \ \ [r\C1ur'0r.1 * **f,- 1 'troy. ui-.\"r =) YL = lot*L ' cr\s.r -?.otJ."t \o {,-Fr'"- uk",- ') \t-H . -\co "rL .1 - (w K^ c,u-o^- * rdo -.t-).2 4- -2. Sx lo Sx!o- - X zx = ;r-o'; = -'<- HC1 [so, + Dh- .L =) X: 9.30 x lo XL Sxl-f, -+ AO (-1 , Lou_J = t. z1o! v^L + +\n\t'^1 t- A5.63 .i,,i * S0" o. / 11 etc( -6 ,.xo xlo t1 2 fDR : I 4 o.'{ t1 c2\\sNt\rJ 0.211 +JiN03 ruL ----r tS' tK^ = -.-+ 1r\ ' 5.06 5.5s $ = 8.tff -e tu: lfwoL /0,1s- il NooH (r<, = s. =)t o /-+ 6x \ FZf| I o,s I HU_ + "'t ----'i t{ ' '---' t\\ : 1 \""t c. ,loo r*L 1 u4 "r r t- L'\' fl' o. ts 0. go n.oo HJA !4-4r'."affi llnl '=:Z^-- l*rn\ --+ 1*= a 16r I rtir. is d'o*''^at"L --.=) 3r.\\ouJ 1..-l .0oq t-t-U -\ A --- ") - l*J^) t. TL pl"*ro^ w:\\ ,t\o..L "t"^6"*a 'i's coloT- h f-%{ o*- t*"*- 1 t" v*I"c"$- ''," -'\o x {e.a*- "-l * '*0"^ }"'""*- ' ", [r;l -- 4 t*-{ ro ) ,tq, t*h " "A # = t<"- 't -- t ll \. : o.'{Yo''l = '41ot ".^oL +tq. **oU = o' 'i * o'2 = 9Yl5t ""oL .L o'5 af f rsrl rnote$- l_., t-' ) z) l -:_.1 ,> u=:>-, -- l*J \ vL '* tYoaa t+t4^- \.t at{ . I ,.iql;! = '{-J "''oL tH,t2.s)" {l\' .lpRo + hX \r\ | -- | (-+'_) _\ a.^1 lllJ"\ LrnJ = 42.52-0 = 3.sz LH}:) ',L =) 1" t'o &"'''r.an'- r b\ ue- 2 tt.n }e\tto" 'r'o 3.<z Ao= 33 t\